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Sir William Crookes (; 17 June 1832 – 4 April 1919) was an English chemist and physicist who attended the Royal College of Chemistry, now part of Imperial College London, and worked on spectroscopy. He was a pioneer of , inventing the Crookes tube, which was made in 1875. This was a foundational discovery that eventually changed the whole of chemistry and physics.
He is credited with discovering the element thallium, announced in 1861, with the help of spectroscopy. He was also the first to describe the spectrum of terrestrial helium, in 1865. Crookes was the inventor of the Crookes radiometer but did not discern the true explanation of the phenomenon he detected. Crookes also invented a 100% ultraviolet blocking sunglass lens. For a time, he was interested in spiritualism and became president of the Society for Psychical Research.
Joseph Crookes had had five children with his first wife; two sons from that marriage, Joseph and Alfred, took over the tailoring business, leaving William free to choose his own path. In 1848, at age 16, Crookes entered the Royal College of Chemistry (now the Imperial College chemistry department) to study organic chemistry. Crookes lived with his parents about three miles from the College in Oxford Street. His father's shop was about half a mile away. Crookes paid £25 for his first year's tuition and had to provide his own apparatus and some of the more expensive chemicals. At the end of his first year, Crookes won the Ashburton scholarship which covered his second year's tuition. At the end of his second year, Crookes became a junior assistant to August Wilhelm von Hofmann, doing laboratory demonstrations and helping with research and commercial analysis. In October 1851, Crookes was promoted to senior assistant, a position he held until 1854.
Although Crookes revered Hofmann, he did not share his primary interest in organic chemistry. One of Crookes's students was the Reverend John Barlow, Secretary of the Royal Institution, who chose to take a course in analytical chemistry. Through Barlow, Crookes met scientists such as George Gabriel Stokes and Michael Faraday. Such friends reinforced Crookes's interest in optical physics which was respected by Hofmann. By 1851, Crookes's interest in photography and optics caused his father to build him a laboratory in the garden at home for his research.
When Crookes embarked upon original work, it wasn't in organic chemistry, but rather into new compounds of selenium. These were the subject of his first published papers, in 1851. He worked with Manuel Johnson at the Radcliffe Observatory in Oxford in 1854, where he adapted the recent innovation of wax paper photography to machines built by Francis Ronalds to continuously record meteorological parameters. In 1855 he was appointed lecturer in chemistry at the Chester Diocesan Training College.
In April 1856 Crookes married Ellen, daughter of William Humphrey of Darlington. Since staff at Chester were required to be bachelors, he had to resign his position. William's father, Joseph Crookes, gave the couple a house at 15 Stanley Street, Brompton. Ellen's mother, Mrs. Humphrey, lived with them for the rest of her life, nearly forty years. A devoted couple, William and Ellen Crookes had six sons and three daughters. Their first child, Alice Mary (born 1857, later Mrs. Cowland) remained unmarried for forty years, living with her parents and working as an assistant to her father. Two of Crookes's sons became engineers, and two lawyers.
Married and living in London, Crookes sought to support his new family through independent work as a photographic chemist. In 1859, he founded the Chemical News, a science magazine which he edited for many years and conducted on much less formal lines than was usual for the journals of scientific societies. Between 1864 and 1869, he was also involved with the Quarterly Journal of Science. At various times he edited the Journal of the Photographic Society and the Photographic News.
His first important discovery was that of the element thallium, made with the help of flame spectroscopy. Crookes discovered a previously unknown element with a bright green emission line in its spectrum. He named the element thallium, from Greek language θαλλός, thallus]], meaning "a green shoot or twig". Crookes's findings were published on 30 March 1861.Crookes, William (30 March 1861) "On the existence of a new element, probably of the sulphur group," Chemical News, vol. 3, pp. 193–194; reprinted in: Crookes, William (18 May 1861) "Further remarks on the supposed new metalloid," Chemical News, vol. 3, p. 303.Crookes, William (19 June 1862) "Preliminary researches on thallium," Proceedings of the Royal Society of London, vol. 12, pages 150–159.
Thallium was also independently discovered by Frenchman Claude Auguste Lamy, who had the advantage of access to large amounts of materials via his brother-in-law, Charles Frédéric Kuhlmann. Both Crookes and Lamy isolated the element in 1862.Lamy, A. (16 May 1862) "De l'existencè d'un nouveau métal, le thallium," Comptes Rendus, vol. 54, pages 1255–1262.
Crookes was elected a fellow of the Royal Society in 1863. Crookes wrote a standard treatise on Select Methods in Chemical Analysis in 1871.
In 1866, Adolf Erik Nordenskiöld identified a rare mineral from Skrikerum as a selenide of copper, thallium, and silver (), and named the mineral crookesite in honor of Sir William Crookes.
Crookes developed the Crookes tube,The difference between "Crookes tubes" and "" is this: In a Geissler tube the exhaustion is very much less than in a Crookes tube, the light which we see in the Geissler tube being due to the luminescence of the residual gas. (Transactions, Volume 9. Hertfordshire Natural History Society and Field Club. The Club, 1898. Page 136.) investigating . He published numerous papers on spectroscopy and conducted research on a variety of minor subjects. In his investigations of the conduction of electricity in low pressure gases, he discovered that as the pressure was lowered, the negative electrode (cathode) appeared to emit rays (the so-called "cathode rays", now known to be a stream of free , and used in cathode-ray display devices). As these examples indicate, he was a pioneer in the construction and use of for the study of physical phenomena.Alexander E. Outerbridge, Jr., A Fourth State of Matter. Lecture delivered before the Franklin Institute, 17 February 1881. Journal of the Franklin Institute of the State of Pennsylvania, Volume 81. By Franklin Institute (Philadelphia, Pa.). Page 287+. He was, as a consequence, one of the first scientists to investigate what is now called a plasma and identified it as the fourth state of matter in 1879.William Crookes, On Radiant Matter. Lecture delivered before the British Association for the Advancement of Science, at Sheffield, Friday, 22 August 1879. The Popular Science Monthly, Volume 16. D. Appleton, 1880. Pg157+ He also devised one of the first instruments for studying nuclear radioactivity, the spinthariscope.Crookes, W. Certain Properties of the Emanations of Radium. Chemical News; Vol. 87:241; 1903.
Crookes investigated the properties of , showing that they travel in straight lines, cause fluorescence when they fall on some substances, and that their impact can produce great heat. He believed that he had discovered a fourth state of matter, which he called "radiant matter",Radio-activity induced by the oscillatory discharge, or, The subsequent radio-active emanation from substances exposed to the Tesla oscillatory discharge. Harry Marshall Diemer, Ralph Stuart Cooper. Cornell University, 1903. Page 43+. but his theoretical views on the nature of "radiant matter" were to be superseded.Chemist & Druggist, Volume 60. Benn Brothers., 1902. Pg 268. He believed the rays to consist of streams of particles of ordinary molecular magnitude. It remained for Sir J. J. Thomson to expound on the subatomic nature of cathode rays (consisting of streams of negative electronsNegatively electrified particles whose mass is only 1/1840 that of a hydrogen atom). Nevertheless, Crookes's experimental work in this field was the foundation of discoveries which eventually changed the whole of chemistry and physics.
Crookes's attention had been attracted to the vacuum balance in the course of his research into thallium. He soon discovered the phenomenon which drives the movement in a Crookes radiometer, in which a set of vanes, each blackened on one side and polished on the other, rotate when exposed to radiant energy. Crookes did not, however, provide the true explanation of this apparent "attraction and repulsion resulting from radiation".., Improvement in Apparatus For Indicating The Intensity of Radiation
After 1880, Crookes lived at 7 Kensington Park Gardens in the fashionable area of Notting Hill. His household included a large multigenerational family and a number of servants. There all his later work was done, in what was then "the finest private laboratory in Britain". It comprised an entire floor of the house and included three interconnected laboratory rooms, for chemistry, physics, and mechanical construction, and a library. Crookes was able to purchase the house and build the laboratory because of his income from the National Guano Company and from various patents.
By 1880 Crookes employed a paid full-time scientific assistant (first Charles Gimingham and after 1883 James Gardiner). He was also helped by his daughter Alice, who was "adept at fractionating rare earth elements" and "no mean interpreter of spectrum".
His daily routine was to manage his commercial affairs in the morning, do further business or go to scientific meetings in the afternoon, eat dinner at 7, work in his library from 8 to 9, and then in the laboratory until after midnight. From his home, Crookes could easily reach the Chemical News offices, the Royal Society, the Chemica Society, and the Athenaeum Club.
On 16 January 1884, Crookes's father died. Crookes's daughter Florence died of scarlet fever in the same week. Joseph Crookes's estate was left in trust, divided between his three surviving sons, Alfred, William and Frank. Combined with his previous income, this ensured that Crookes was very well off.
In 1886, Crookes was elected as a member to the American Philosophical Society.
Crookes was named president of the British Association for the Advancement of Science in 1898. In his inaugural address, he outlined in detail a coming catastrophe: The wheat-eating peoples of the world were going to start running out of food in the 1930s. The reason, he said, was a dearth of nitrogen fertilizer available from natural sources. Crookes called on chemists to develop new ways of making fertilizer from the enormous stock of nitrogen in the atmosphere (which is roughly 80 percent nitrogen). His remarks on the coming famine achieved wide distribution in the press and were turned into a popular book. Scientists addressing the problem in the first years of the twentieth century included Kristian Birkeland, whose technology helped found Norsk Hydro, and Fritz Haber and Carl Bosch, whose Haber–Bosch process forms the foundation of today's nitrogen fertilizer industry.
In 1903, Crookes turned his attention to the newly discovered phenomenon of radioactivity, achieving the separation from uranium of its active transformation product, uranium-X (later established to be protactinium). Crookes observed the gradual decay of the separated transformation product, and the simultaneous reproduction of a fresh supply in the original uranium. At about the same time as this important discovery, he observed that when "p-particles", ejected from radio-active substances, impinge upon zinc sulfide, each impact is accompanied by a minute scintillation, an observation which forms the basis of one of the most useful methods in the detection of radioactivity.
In 1913, Crookes created an ultraviolet blocking lens made from glass containing cerium, but only lightly tinted. They were an unintended by-product of Crookes's research to find a lens glass formulation that would protect glass workers from cataracts. Crookes tested more than 300 formulations, NIST each numbered and labelled. Crookes Glass 246 was the tint recommended for glassworkers. The best-known Crookes tints are A (withdrawn due to its uranium), A1, B, and B2, which absorb all ultraviolet below 350 nm while darkening visual light. Crookes's samples were made by Whitefriars, London, stained glass makers, and Chance Brothers, Birmingham.
Crookes died in 1919 at the age of 86.
Crookes was possibly influenced by the death of his younger brother Philip in 1867 at 21 from yellow fever contracted while he was on an expedition to lay a telegraph cable from Cuba to Florida.Janet Oppenheim. (1988). The Other World: Spiritualism and Psychical Research in England, 1850–1914. Cambridge University Press. pp. 343–347. John Hannavy. (2007). Encyclopedia of Nineteenth-Century Photography. Routledge. p. 350. "Crookes' beloved younger brother had died in 1867 and the scientist hoped that spiritualism could provide a reunion. Although warned of the risk of ridicule, Crookes announced his intent to investigate mediums."
In 1867, influenced by Cromwell Fleetwood Varley, Crookes attended a séance to try to get in touch with his brother.Sherrie Lynne Lyons. (2010). Species, Serpents, Spirits, and Skulls: Science at the Margins in the Victorian Age. State University of New York Press. p. 92. "Crookes appears to have been initially attracted to spiritualism when his youngest brother, whom he was quite close to, died of yellow fever. Brought up with the traditional Christian belief in the afterlife, Crookes was persuaded to attend a séance in 1867 to try to make contact with his brother."Martyn Jolly. (2006). Faces of the Living dead: The Belief in Spirit Photography. Miegunyah Press. p. 30. "In 1867, he was devastated by the death of his much-loved youngest brother who, at the age of twenty-one. had caught yellow fever while laying a submarine telegraph cable in Cuba. At the time, Crookes was collaborating with a fellow electro-physicist Cromwell Fleetwood Varley, who was a pioneer of intercontinental telegraphy, as well as a clairvoyant. He persuaded Crookes to try to get in touch with his dead brother by spiritualist means."
Between 1871 and 1874, Crookes studied the mediums Fox sisters, Florence Cook, and Daniel Dunglas Home. After his investigation, he believed that the mediums could produce genuine paranormal phenomena and communicate with spirits.Daniel Cohen. (1971). Masters of the Occult. Dodd, Mead & Company. p. 111. Andrew Neher. (2011). Paranormal and Transcendental Experience: A Psychological Examination. Dover Publications. p. 214. "William Crookes, the noted English physicist, had endorsed Catherine Fox as genuine... Crookes also endorsed several other mediums who were later exposed, including Anna Eva Fay (who was exposed more than once and who eventually explained how she duped Crookes), Florence Cook (who was the subject of more than one expose), and D. D. Home." Psychologists Leonard Zusne and Warren H. Jones have described Crookes as gullible as he endorsed fraudulent mediums as genuine.Leonard Zusne; Warren H. Jones. (2014). Anomalistic Psychology: A Study of Magical Thinking. Psychology Press. p. 216. "The fact is that William Crookes, although very good at physics experiments, was rather weak on drawing inferences and on theorizing. Besides, he was gullible. He endorsed several mediums in spite of their demonstrated trickery. Having witnessed a single seance with Kate Fox, he became convinced that the Fox sisters' rappings were genuine."
The anthropologist Edward Clodd noted that Crookes had poor eyesight, which may have explained his belief in spiritualist phenomena and quoted William Ramsay as saying that Crookes is "so shortsighted that, despite his unquestioned honesty, he cannot be trusted in what he tells you he has seen."Edward Clodd. (1917). The Question: A Brief History and Examination of Modern Spiritualism. Grant Richards, London. p. 100 Biographer William Hodson Brock wrote that Crookes was "evidently short-sighted, but did not wear spectacles until the 1890s. Until then he may have used a monocle or pocket magnifying glass when necessary. What limitations this imposed upon his psychic investigations we can only imagine."
After studying the reports of Florence Cook, the science historian Sherrie Lynne Lyons wrote that the alleged spirit "Katie King" was at times Cook herself and at other times an accomplice. Regarding Crookes, Lyons wrote, "Here was a man with a flawless scientific reputation, who discovered a new element, but could not detect a real live maiden who was masquerading as a ghost".Sherrie Lynne Lyons. (2010). Species, Serpents, Spirits, and Skulls: Science at the Margins in the Victorian Age. State University of New York Press. p. 101. Cook was repeatedly exposed as a fraudulent medium but she had been "trained in the arts of the séance" which managed to trick Crookes.M. Lamar Keene. (1997). The Psychic Mafia. Prometheus Books. p. 64. "The most famous of materialization mediums, Florence Cook-- though she managed to convince a scientist, Sir William Crookes, that she was genuine-- was repeatedly exposed in fraud. Florence had been trained in the arts of the séance by Frank Herne, a well-known physical medium whose materializations were grabbed on more than one occasion and found to be the medium himself." Some researchers such as Trevor H. Hall suspected that Crookes had an affair with Cook.Trevor H. Hall. (1963). The Spiritualists: The Story of Florence Cook and William Crookes. Helix Press.John Sladek. (1974). The New Apocrypha: A Guide to Strange Sciences and Occult Beliefs. Panther. p. 194. "Crookes was forty-one, and his wife was pregnant with their tenth child. Florence was eighteen and pretty, and willing to spend considerable time at Crookes home, locked into a dark room alone with him, while beautiful apparitions were shown to him. The man Florence had secretly married, Captain Corner, put an unspiritual construction on the proceedings, and gave Crookes a beating. By 1875 the situation was becoming obvious to outsiders, who published hints that the next manifestation might be an infant phenomenon. As for the apparitions, no one but Crookes is reported to have ever seen them ... By 1880 Florence had been exposed as a fraud by Sir George Sitwell."Amy Lehman. (2009). Victorian Women and the Theatre of Trance: Mediums, Spiritualists. McFarland. p. 158. Crookes took 44 photographs of "Katie King", in some of which he, or Florence Cook appear alongside her. He described in detail the physical differences between the spirit and her medium. The fact that some of these photographs, which still exist, show a Katie King who looks almost identical to Florence Cook calls Crookes's judgment, not to mention his veracity, into question. Skeptics at the time who were convinced that Florence was a fake thought that either Crookes was being completely hood-winked or that he had agreed to perpetrate the fraud with Florence. And the only explanation in either case had to be that Crookes was smitten with Florence—at the very least besotted with her and probably having an affair."
In a series of experiments in London, England at the house of Crookes in February 1875, the medium Anna Eva Fay managed to fool Crookes into believing she had genuine psychic powers. Fay later confessed to her fraud and revealed the tricks that she had used.Massimo Polidoro. (2000). Anna Eva Fay: The Mentalist Who Baffled Sir William Crookes. Skeptical Inquirer 24: 36–38. Regarding Crookes and his experiments with mediums, the magician Harry Houdini suggested that Crookes had been deceived.Harry Houdini. (2011, originally published 1924). A Magician Among the Spirits. Cambridge University Press. p. 205. "There is not the slightest doubt in my mind that this brainy man was hoodwinked, and that his confidence was betrayed by the so-called mediums that he tested. His powers of observation were blinded and his reasoning faculties so blunted by his prejudice in favor of anything psychic or occult that he could not, or would not, resist the influence." The physicist Victor Stenger wrote that the experiments were poorly controlled and "his desire to believe blinded him to the chicanery of his psychic subjects."Victor J. Stenger. (1990). Physics and Psychics: The Search for a World Beyond the Senses. Prometheus Books. pp. 156–157.
In 1897, John Grier Hibben wrote that Crookes's idea of ether waves explaining telepathy was not a scientific hypothesis "he presents no facts to indicate its probability or to save it from being relegated to the sphere of bare conjecture."Hibben, J. G. (1897). Review of Presidential Address to the Society for Psychical Research, by W. Crookes. Psychological Review 5: 362–387.
In 1916, William Hope tricked Crookes with a fake spirit photograph of his wife. Oliver Lodge revealed there had been obvious signs of double exposure, the picture of Lady Crookes had been copied from a wedding anniversary photograph, but Crookes was a convinced spiritualist and claimed it was genuine evidence for spirit photography.
The physiologist Gordon Stein suspected that Crookes was too ashamed to admit he had been duped by the medium Florence Cook or that he conspired with her for sexual favors. He also suggested that Crookes had conspired with Anna Eva Fay. He noted that contrary to popular belief, Hope had been exposed as a fraud on several occasions. Stein concluded that all feats of Hope were conjuring tricks.
Crookes joined the Society for Psychical Research, becoming its president in the 1890s: he also joined the Theosophical Society and The Ghost Club, of which he was president from 1907 to 1912. In 1890 he was initiated into the Hermetic Order of the Golden Dawn.
Middle years
Crookes was effective in experimentation. The method of Spectroscopy, introduced by Robert Bunsen and Gustav Kirchhoff, was received by Crookes with great enthusiasm and to great effect.
, 1902]]
Later years
On 13 August 1894, John William Strutt, 3rd Baron Rayleigh and William Ramsay announced the detection of a new gas in the atmosphere. On 31 January 1895 they made a full report to the Royal Society on the new gas, argon. In addition, William Crookes, who had been asked to examine a sample, presented on the spectra of argon, reported that argon displayed two distinct spectra. In this way, Crookes identified the first known sample of terrestrial helium and established its correspondence to observations of solar helium. The discovery of argon and of helium led to identification of the noble gases and the reorganization of the periodic system.
Crookes himself suggested a design for a Periodic table in the style of a space lemniscate in 1898.
Crookes was knighted in 1897.
Spiritualism
Crookes became interested in spiritualism in the late 1860s, and was most strongly involved around 1874–1875. Eric Deeson notes that Crookes's studies of the occult are related to his scientific work on radiometry in that both involved the detection of previously undiscovered forces.
(1993). 9780879758639, Prometheus Books. ISBN 9780879758639 In a review, biographer William Brock wrote that Stein made his "case against Crookes and Home clearly and logically."Brock, William. (1994). Was Crookes A Crook?. Nature 367: 422–422.
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Categories: 1832 Births, 1919 Deaths, 19th-century British Chemists, 19th-century British Physicists, 19th-century English People, 20th-century British Chemists, 20th-century British Physicists, 20th-century English Scientists, Academics Of The University Of Chester, Alumni Of Imperial College London, Burials At Brompton Cemetery, Discoverers Of Chemical Elements, English Physical Chemists, English Physicists, English Spiritualists, Fellows Of The Royal Society, Foreign Associates Of The National Academy Of Sciences, Knights Bachelor, Members Of The Order Of Merit, British Parapsychologists, People From Notting Hill, People Involved With The Periodic Table, English Plasma Physicists, Presidents Of The Royal Society, Recipients Of The Copley Medal, Royal Medal Winners, British Scientific Instrument Makers, Scientists From London, Thallium, Rare Earth Scientists, Members Of The American Philosophical Society
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